Samsung Electronics Standards for Control of Substances with Environmental Impacts within Products (SEC Registration No. 0QA-2049) (For Cooperating Suppliers) The 3rd Edition (February 14, 2005) CS Management Center Products Environment Technology Team List of Contents 1. Preface 2. Purpose 3. Scope 4. Definitions 5. Management and Application Standard 5. A. The Standard for Control of Substances with Environmental Impacts within Products 5. B. List of the Substances with Environmental Impacts for Control and Management 5. C. Application of Standards for Substances with Environmental Impacts within Products 5. D. Application of Standards for Packaging Materials 5. E. Application of Standards for Battery and Accumulators Appendix. Detailed chemical list with CAS-No. The Leader for Superior Quality CS Management Center 1. Preface In order to sell our products to the world marketplace, Samsung Electronics must guarantee and verify environmental compliance for all parts and components of finished products to prevent adverse effects on human health and the environment. The following list of substances with environmental impacts was developed based on global regulatory and customer requirements. 2. Purpose This document is to provide information and requirements for environmental material compliance on Samsung Electronics products. The following standard specifies restrictions on substances and materials used in manufacture of Samsung Electronics products, including bans, restrictions, and reporting of certain substances as constituents of parts, components, materials and products supplied into Samsung Electronics. 3. Scope This standard applies to all parts, components, and materials (including packaging materials), which are used to develop products to put in the market. The application scope is specified for each substance in the standard. The standard also applies to all products designed, developed and manufactured by the company regardless of region. 4. Definitions A. Substances with Environmental Impacts : Substances or groups of substances which are regulated and restricted for use by the company due to their adverse effects on the human body and the environment. B. Management Classification 1) Class: Classification of the substance category by regulatory status z Class I : Substances which are regulated by EU Directive RoHS (Restriction of the use of certain hazardous substances in electrical and electronic equipment, Directive 2002/95/EC). The substances include cadmium, lead, mercury, hexavalent chromium, and PBB and PBDE The Leader for Superior Quality CS Management Center z : Detailed Analysis Class II : Substances which are designated for restricted use by regulations or other than by EU Directive RoHS z Class III : Substances whose uses are monitored and reported to develop appropriate measures for future restrictions and phase-out programmes 2) Level: Classification of application scope and implementation date in a Class z z Level 1 : The standard has been taken into effect on application scope specified by Level. Level 2 : The standard shall be effective on regulated application at a certain time designated in Level 2 Exemptions: In cases where no alternative is available and substances are used for a specific characteristic, appearance or quality, the substance can be used until appropriate measures or alternatives are developed z C. Threshold limit : The maximum concentration level at which the presence of a substance can be tolerated in a material. This level is provided for detection sensitivity errors of instrumental measurements and trace impurities in a material. Threshold limits are criteria for fail or pass of material qualification. Only concentrations less than threshold limits will be accepted for qualified material. D. Detailed Analysis : Detailed analysis is a test using equipments with high precision such as ICP, IC, UV/VIS and GC/MS. E. ICP (Inductively Coupled Plasmas) Analysis : ICP is a method of atomic emission spectrometry for analysis of heavy metals in a given sample. When plasma energy, generated by Argon gas, is given to an analysis sample, the atoms are excited. When the excited atoms return to low energy position, emission rays (spectrum rays) are released and the emission rays that correspond to the photon wavelength are measured. The element type is determined by the position of the photon rays, and the content of each element is determined by the ray’s intensity. There can be errors in results depending on the type of acid used and the pre-treatment method. It is therefore necessary to check the recommended pre-treatment method for the substance classification of the sample. The Leader for Superior Quality CS Management Center F. IC (Ion Chromatography) : Ion Chromatography (IC) is the separation and quantification of anions and cations using Liquid Chromatography (LC). LC is an analytical technique based on the separation of the components of a mixture in solution by selective absorption. There are basically three modes of separation: liquid/liquid, liquid/solid, and molecular size. Once the components have been separated they are measured by a conductivity detector. G. UV/VIS spectrometry : UV/VIS spectrometry is a tool that measures the wavelength-dependant absorption of light in the visible or ultraviolet region. It is usually applied to identify molecules and inorganic ions or complexes in solution. The UV-VIS spectra have broad bands that are of limited use for sample identification but are very useful for the quantitative measurements. Measuring the transmittance at some wavelengths, and applying the Beer-Lambert law equations, the concentration of the solvent in the solution can be determined. H. GC/MS (Gas chromatography with Mass spectrometry) : Gas Chromatography–Mass Spectrometry (GC-MS) is an analytical technique involving the use of both Gas Chromatography (GC) and Mass Spectrometry (MS), the former to separate a complex mixture into its components and the latter to deduce the atomic weights of those components. It is particularly useful in identifying organic compounds. (LRGC/MS : Low Resolution GC/MS, HRGC/MS : High Resolution GC/MS) The Leader for Superior Quality CS Management Center 5. Management and Application Standard A. The Standard for Substances with Environmental Impacts within Products 1) The company manages the substances with environmental impacts by classifying them as either Class Ⅰ, Ⅱ or 3 and Level 1, 2 as exemptions. 2) The measures and schedules for management of the substances with environmental impacts (refer to Table 1 and 2) are specified for each substance. The standard and management method will be regularly revised and further consolidated to comply with global regulatory changes, after notifying the GBMs (Global Business Management). 3) The company will provide a grace period for improvements until alternatives or other methods are available. 4) The standard provides maximum concentration levels for management of substances. Maximum concentration levels are determined after considering likely levels of impurities in materials and known error factors in the measurement instruments / methods used to assess them. 5) The listed substances of the standard are determined and managed at a corporate level, so GBMs must include the substances listed in the standard as a minimum requirement on the GBM’s own list and rules. The Leader for Superior Quality CS Management Center B. List of Substances with Environmental Impacts for Control and Management Table 1. Banned and restricted substances Type Substance/Material Cadmium and compounds EU RoHS Directive EU Packaging Directive EU Battery Directive OSPAR Priority Chemicals EU RoHS Directive California Proposition 65 EU Packaging Directive EU Battery Directive OSPAR Priority Chemicals EU RoHS Directive EU Packaging Directive EU Battery Directive OSPAR Priority Chemicals EU RoHS Directive EU Packaging Directive OSPAR Priority Chemicals EU RoHS Directive OSPAR Priority Chemicals EU RoHS Directive OSPAR Priority Chemicals Regulation Lead and compounds Class Ia Mercury and compounds Hexavalent chromium and compounds Polybrominated biphenyls (PBBs) Polybrominated diphenylethers (PBDEs) Polychlorinated biphenyls (PCBs) Polychlorinated terphenyls (PCTs) Polychrlorinated naphthalenes (PCNs, with three or more chlorine substituents) Ozone layer depleting substances (CFCs, HCFCs, Halons) Class IIb Asbestos Formaldehyde Short-chain chlorinated paraffins (Alkane 10∼13 carbon chain) Azo colorants Nickel and compounds Organic tin compounds Arsenic and compounds EU Directive 76/769/EEC OSPAR Priority Chemicals Montreal Protocol EC Regulation 2037/2000 EU Directive 76/769/EEC German Regulations EU Directive 76/769/EEC OSPAR Priority Chemicals EU Directive 2002/61/EC EU Directive 94/27/EC EU Directive 76/769/EEC OSPAR Priority Chemicals EU Directive 76/769/EEC * The substances listed in Table 1 are restricted for use in Samsung Electronic Co., Ltd. These substances are prohibited for deliberate use in the production of products, parts and materials bought or manufactured by the company. For unintentional and inevitable uses (i.e. impurities), a threshold level is provided for each substance. If the concentrations of substances are less than the appropriate threshold levels, then the item can be considered as qualified for use in production. a Class I 6 substances regulated by RoHS Directive 2002/95/EC. The substances are officially controlled from the implementation date and will be phased out by June 30, 2005. Class II Substances other than those regulated by RoHS Directive 2002/95/EC. Most of them are hardly used but their use will be officially controlled from the implementation dates. bThe Leader for Superior Quality CS Management Center Table 2. Monitored and reportable substances Type Phthalates Polyvinyl chloride (PVC) Beryllium and compounds Other chlorinated flame retardantsClass III Other brominated flame retardants(BFRs) • TBBP-A: Tetrabromobisphenol-AaSubstance/Material 1. For PVC, its ban of use in packaging implementedfrom May 14, 2004 2. The company will monitor PVC use in products and develop phase-out plan by the end of 2005 1. Phase-out plan of brominated flame retardants of high concern, such as TBBP-A, will be developed after monitoring of its use 2. Phase-out plan for all other BFRs planned for end of 2005, based on available substitutes, which are both non-hazardous to health or the environment, and are technically feasible for use without unacceptable loss of product quality and performance a Class III Monitored and reportable substances, which are monitored and reported to reduce the use in products. The company will conduct research on development of a substitute and phase-out plan for Class III substances. The Leader for Superior Quality CS Management Center C. Application of Standards for Substances with Environmental Impacts within Products C.1. Cadmium and compounds ( Cd ) Example use: Pigment, anti-corrosion surface treatment, electric and electronic materials, optical material, stabilizer, stabilizer for PVC, plating, electrode, etc. Type Threshold Limit (mg/kg = ppm) Application 5 ppm Internal / external plastics, rubber, stabilisers, colouring agents, dyes / pigments, paints or surface coating / plated plastic, packaging / batteries Implementation date Exemption May 14, 2004 January 1, 2005 Level 1 80 ppm Plated metal Level 2 80 ppm All applications except for level 1 - The Cadmium plating of electric / electronic contacts which requires a high safety and reliability standard for which no alternative materials exist. - Cadmium in optical and filter glass The Leader for Superior Quality CS Management Center C.2. Lead and compounds ( Pb ) Example use: Rubber hardener, pigment, paint, lubricant, plastic stabilizer, battery material, free-machining alloy, free-cutting steels, optical materials, X-ray shielding in CRT glass, electrical solder materials, mechanical solder, curing agent, vulcanizing agent, resin stabilizer, plating, metal alloy, resin additives Type Threshold Limit (mg/kg = ppm) Application 100 ppm Internal / external plastics, rubber, stabilizers, colouring agents, dyes / pigments, paints, coating Level 1 800 ppm PWB board surface, surface coating / plating (external electrodes, lead wires, etc), alloy, solder paste and other assembly materials, which are not specified in Exemption Implementation date Exemption May 14, 2004 January 1, 2005 Level 2 800 ppm All applications except for level 1 - Lead in glass of cathode ray tubes, electronic components and fluorescent tubes - Lead as an alloying element in steel containing up to 0.35% lead by weight, aluminium containing up to 0.4 % lead by weight and as a copper alloy containing up to 4% lead by weight. - Lead in high melting temperature type solders (i.e. lead based alloys containing 85 % by weight or more lead), - Lead in solders for servers, storage and storage array systems, network infrastructure equipment for switching, signalling, transmission as well as network management for telecommunications, - Lead in electronic ceramic parts (e.g. piezoelectronic devices) - Lead used in compliant pin connector systems. - Lead as a coating material for the thermal conduction module c-ring. - Lead in optical and filter glass. - Lead in solders consisting of more than two elements for the connection between the pins and the package of microprocessors with a lead content of more than 80% and less than 85% by weight. - Lead in solders to complete a viable electrical connection between semiconductor die and carrier within integrated circuit Flip Chip packages. The Leader for Superior Quality CS Management Center C.3. Mercury and compounds ( Hg ) Example use: fluorescent bulb, contact point material, pigment, anti-corrosion, high-efficiency phosphor, antibacterial treatment Type Threshold Limit (mg/kg = ppm) Application Level 1 800 ppm Level 2 800 ppm Internal / external plastics, rubber, colouring All applications except for level 1 agents, pigments / dyes, paints, inks, packaging / batteries Implementation date Exemption May 14, 2004 January 1, 2005 - Mercury in compact fluorescent lamps not exceeding 5 mg per lamp - Mercury in straight fluorescent lamps for general purposes not exceeding · halophosphate 10 mg · triphosphate with normal lifetime 5 mg · triphosphate with long lifetime 8 mg - Mercury in straight fluorescent lamps for special purpose C.4. Hexavalent chromium and compounds ( Cr+6 ) Example use: Pigment, paint, ink, catalyst, plating, anti-corrosion surface treatment, dye, paint dryer, surface treatment, chromate treatment, paints adhesion enhancement, anti-corrosion Type Threshold Limit (mg/kg = ppm) Application Level 1 800 ppm Level 2 800 ppm Internal / external plastics, rubber, coloring All applications except for level 1 agents, pigments / dyes, paints, inks, packages / batteries Implementation date Exemption May 14, 2004 January 1, 2005 - Hexavalent chromium as an anti-corrosion of the carbon steel cooling system in absorption refrigerators The Leader for Superior Quality CS Management Center C.5. Polybrominated biphenyls (PBBs) Example use: flame retardant Type Level 2 Threshold Limit (mg/kg = ppm) Application Implementation date 100 ppm All applications (e.g. flame retardants) February 1, 2005 C.6. Polybrominated diphenylethers (PBDEs) Example use: flame retardant Type Level 2 Threshold Limit (mg/kg = ppm) Application Implementation date 100 ppm All applications (e.g. flame retardants) February 1, 2005 C.7. Polychlorinated biphenyls (PCBs) / polychlorinated terphenyls (PCTs) / polychlorinated naphthalenes (PCNs, with three or more chlorine substituents) Example use: insulation oil, lubricant oil, electrical insulation medium, solvent, electrolytic solution, stabilizer, electricity, flame retardant, water-resistant, insulator Type Level 1 Threshold Limit (mg/kg = ppm) Application Implementation date C.8. Ozone layer depleting substances (CFCs, HCFCs, Halons) Example use: refrigerant, foaming agent, extinguishant, solvent cleaner 50 ppm All applications May 14, 2004 Type Level 1 Threshold Limit Application Implementation date Non-use All applications May 14, 2004 The Leader for Superior Quality CS Management Center C.9. Asbestos Example use: Brake lining pad, insulator, filler, abrasive, pigment, paint, talc, adiabatic material Type Level 1 Threshold Limit Application Implementation date Non-use All applications (e.g. filler, insulating material) May 14, 2004 C.10. Formaldehydes Example use: antiseptic solution, preservative Type Threshold Limit (mg/kg = ppm) Application Level 1 0.1ppm in a test chamber. Exporting wooden products into EU member states Implementation date C.11. Short-chain chlorinated paraffins, alkane 10 ∼ 13 carbon chain Example use: plasticizer for PVC, flame retardant May 14, 2004 Level 2 0.1ppm in a test chamber. phenolic resin Type Level 1 Threshold Limit (mg/kg = ppm) Application Implementation date C.12. Azo colorants Example use: pigment, dyes, colorants 1000 ppm Plastic softener or plasticizer, PWBs May 14, 2004 Type Level 1 Threshold Limit (mg/kg = ppm) Application 30 ppm Textile and leather article in prolonged contact with the skin (e.g. belt, straps, grip, etc.) Implementation date May 14, 2004 The Leader for Superior Quality CS Management Center C.13. Nickel and compounds Example use: pigment, paint, optical thin film, reflection coating, battery materials, conductive materials, semiconductors, surface treatment, magnetic thin film, nickel plating, electrode, catalyst, alloy 0.5 ug-Ni/cm2/week Applications (alloys) for the components contacting human skins : External chassis/ case parts Implementation date May 14, 2004 Type Level 1 Threshold Limit Application C.14. Organic tin compounds Example use: antiseptic, anti-oxidizer, antibacterial and antifungal agents, antifoulant, paint, pigment, antistaining Type Level 1 Threshold Limit Application Implementation date Non-use Paints, inks, preservatives, and fungicides May 14, 2004 C.15. Arsenic compounds Example use: pigment, paint, dye, anti-foamer for glass, GaAs semiconductor Type Level 1 Threshold Limit Application Implementation date Non-use Paints, inks, preservatives, and fungicides May 14, 2004 The Leader for Superior Quality CS Management Center D. Application of Standards for Packaging Materials D.1. Cadmium, lead, mercury, hexavalent chromium Threshold limit (mg/kg = ppm) Application Implementation date Exemptions Type Level 1 100 ppm (Sum of Cd, Pb, Hg, and Cr+6 concentrations) All packaging material May 14, 2004 - Packaging entirely made of lead crystal glass - Incidental presence of regulated heavy metals by using recycled material D.2. Ozone layer depleting substances (CFCs, HCFCs, Halons) Example use: blowing agents Type Level 1 Threshold limit Application Implementation Date Non-use All packaging materials May 14, 2004 D.3. PVC (Polyvinyl chloride) Example use: packaging material Type Level 1 Threshold limit Application Implementation Date Non-use All packaging materials May 14, 2004 D.4. BFR (Brominated Flame Retardant) Example use: packaging material Type Level 1 Threshold limit Application Implementation Date Non-use All packaging materials February 1, 2005 The Leader for Superior Quality CS Management Center E. Application of Standards for Battery and Accumulators E.1. Cadmium and compounds Threshold limit (mg/kg = ppm) Application Implementation Date Type Level 1 250 ppm All application in battery and accumulators May 14, 2004 ※ Cadmium-contained battery exceeding the threshold limit will be accepted only if adequately marked or labeled according to applicable regulations. E.2. Lead and compounds Threshold limit (mg/kg = ppm) Application Implementation Date Type Level 1 4000 ppm All applications in battery and accumulators May 14, 2004 ※ Lead-contained battery exceeding the threshold limit will be accepted only if adequately marked or labeled according to applicable regulations. E.3. Mercury and compounds Threshold limit (mg/kg = ppm) Application Implementation Date Exemptions Type Level 1 5 ppm All applications in battery and accumulators May 14, 2004 < 2% by wt. for button cell batteries The Leader for Superior Quality CS Management Center Appendix. Detailed chemical list with CAS-No. Appendix 1. Cadmium and compounds Substance CAS Number Cadmium alloys Cadmium oxide Cadmium sulfide Cadmium carbonate Cadmium chloride Cadmium nitrate Cadmium nitrate tetrahydrate Cadmium sulfate Cadmium stearate Other cadmium compounds and alloys - 1306-19-0 1306-23-6, 8048-07-5 513-78-0 10108--2 10325-94-7 10022-68-1 10124-36-4 2223-93-0 Cadmium 7440-43-9 Appendix 2. Lead and compounds Substance CAS Number Lead; metal 7439-92-1 Lead/Tin alloy - Lead(Ⅱ)oxide 1317-36-8 Lead(Ⅳ)oxide 1309-60-0 Dilead trioxide - Lead(Ⅱ, Ⅳ)oxide 1314-41-6 Lead azide 13424-46-9 Lead(Ⅱ)fluoride 7783-46-2 Lead(Ⅱ)chloride 7758-95-4 Lead(Ⅳ)chloride 13463-30-4 Lead(Ⅱ)iodide 10101-63-0 Lead(Ⅱ)sulfide 1314-87-0 Lead(Ⅱ)cyanide 592-05-2 Lead fluoroborate 13814-96-5 Lead fluosilicate 25808-74-6 Lead nitrate 10099-74-8 Lead carbonate 598-63-0 Lead hydroxcarbonate 1344-36-1 Lead perchlorate 13637-76-8 Lead(Ⅱ) sulfate 7446-14-2, 15739-80-7 Lead oxide sulfate 12202-17-4 Lead(Ⅱ) phosphate 7446-27-7 Lead thiocyanate 592-87-0 Lead(Ⅱ)acetate, trihydrate 6080-56-4 Lead(Ⅱ)acetate 301-04-2 Lead(Ⅳ)acetate 6-67-8 Lead oleate 1120-46-3 Lead stearate 7428-48-0 Lead(Ⅱ)metaborate 10214-39-8 The Leader for Superior Quality CS Management Center Appendix 2. Lead and compounds (cont’d) Substance CAS Number Lead metasilicate 11120-22-2, 22569-74-0 Lead antimonite 13510--9 Lead arsenate(1:1) 7784-40-9 Lead(Ⅱ)arsenite 10031-13-7 Lead chromate; chrome yellow 1344-37-2 Lead molybdate 10190-55-3 Calcium plumbate 12013-69-3 Tetramethyl lead 75-74-1 Tetraethyl lead 78-00-2 Lead hydrocarbonate 1319-46-6 Lead selenide 12069-00-0 Other lead compounds and alloys Appendix 3. Mercury and compounds Substance CAS Number Mercury 7439-97-6 - Mercury alloys;amalgam Mercury(Ⅰ)oxide 15829-53-5 Mercury(Ⅱ)oxide 21908-53-2 Mercury(Ⅰ)chloride 10112-91-1 Mercury(Ⅱ)chloride 7487-94-7 Mercury(Ⅱ)nitrate 10045-94-0 Mercury(Ⅰ)sulfate 7783-35-9 Mercury(Ⅱ)fulminate 628-86-4 Mercury(Ⅱ)acetate 1600-27-7 Methylmercury salts e.g. 22967-92-6 - Ethylmercury salts - Propylmercury salts - Phenylmercury salts - Methoxyethyl-mercury salts - Dialkylmercury Diphenylmercury 587-85-9 Other mercury compounds and alloys The Leader for Superior Quality CS Management Center Appendix 4. Hexavalent chromium and compounds Substance CAS Number Chromium trioxide Lithium chromate Sodium chromate Potassium chromate Potassium chlorochromate Ammonium chromate Copper chromate Magnesium chromate Calcium chromate Strontium chromate Barium Chromate Lead chromate (orange) Lead chromate (yellow) Zinc chromate Sodium dichromate Potassium dichromate Ammonium dichromate Calcium dichromate Dichromic acid Copper chromite Strontium chromate Zinc dichromate other chromium compound 1333-82-0 14307-35-8 7775-11-3 77-00-6 16037-50-6 7788-98-9 138-42-0 13423-61-5 13765-19-0 77-06-02 10294-40-3 1344-38-3 1344-37-2 12018-19-8;13530-65-9; 14018-95-2 10588-01-9 7788-50-9 77-09-05 14307-33-6 13530-68-2 12053-18-8 77-06-02 - - Appendix 5. PBB (polybrominated biphenyls) Substance CAS Number Polybrominated biphenyls (PBBs) 67774-32-7 Appendix 6. PBDE (polybrominated diphenylethers) Substance CAS Number Polybromodiphenyl ether (PBDE) Polybromodiphenyloxide (PBDO) Polybrominated biphenyl ethers (PBBE) Decabromodiphenyl ether (DBDPE) Decabromodiphenyloxide (DBDPO) Octabromodiphenyl ether Octabromodiphenyloxide Hexabromodiphenyl ether Hexabromodiphenyloxide Pentabromodiphenyl ether Pentabromodiphenyloxid - 1163-19-5 32536-52-0 383-60-0 32534-81-9 The Leader for Superior Quality CS Management Center Appendix 7. PCB (polychlorinated biphenyls); PCT (polychlorinated terphenyls); PCN (polychlorinated naphthalenes) Substance CAS Number Polychlorinated bipheyls (PCB) Polychlorinated terpheyls (PCT) Polychlorinated naphtalenes (PCN) 1336-36-3 61788-33-8 - Trichloronaphthalenes 1321-65-9 Tetrachloronaphthalenes 1335-88-2 Pentachloronaphthalenes 1321--8 Octachloronaphthalenes 2234-13-1 The Leader for Superior Quality CS Management Center Appendix 8. Ozone layer depleting substances Group Substance A-Ⅰ Refrigerant Detergent CAS Number B-Ⅰ A-Ⅱ B-Ⅱ CFC raw material B-Ⅲ Solvent E-Ⅰ Disinfectant CFCl3 (CFC-11) 75-69-4 CF2 Cl2 (CFC-12) 75-71-8 C2 F3 Cl3 (CFC-113) 76-13-1 C2 F4 Cl2 (CFC-114) 1320-37-2 76-15-3 C2 F5 Cl (CFC-115) CF3 Cl (CFC-13) 75-72-9 C2 FCl5 (CFC-111) 3-56-3 C2 F2 Cl4 (CFC-112) 28605-74-5 C3 FCl7 (CFC-211) 1301-87-5 C3 F2 Cl6 (CFC-212) 3182-26-1 C3 F3 Cl5 (CFC-213) 23-06-5 C3 F4 Cl4 (CFC-214) 2268-46-4 C3 F5 Cl3 (CFC-215) 1652-81-9 C3 F6 Cl2 (CFC-216) 662-97-2 C3 F7 Cl (CFC-217) 422-86-6 CF2 BrCl (halon-1211) 353-59-3 CF3 Br (halon-1301) 75-63-8 C2 F4 Br2 (halon-2402) 124-73-2 CCl4 (carbon tetrachloride) C2 H3 Cl3 ( 2 ) CH3 Br (methyl bromide) CHFBr2 CHF2 Br CH2 FBr C2 HFBr4 C2 HF2 Br3 C2 HF3 Br2 C2 HF4 Br C2 H2 FBr3 C2 H2 F2 Br2 C2 H2 F3 Br C2 H3 FBr2 C2 H3 F2 Br C2 H4 FBr C3 HFBr6 C3 HF2 Br5 C3 HF3 Br4 C3 HF4 Br3 C3 HF5 Br2 C3 HF6 Br C3 H2 FBr5 C3 H2 F2 Br4 C3 H2 F3 Br3 C3 H2 F4 Br2 C3 H2 F5 Br C3 H3 FBr4 C3 H3 F2 Br3 56-23-5 71-55-6 1868-53-7 1511-62-2 373-52-4 306-80-9 - 3-04-1 124-72-1 - 75-82-1 421-06-7 358-97-4 - 762-49-2 - - - - 431-78-7 - - - - - 460-88-8 - 70192-80-2 C-Ⅱ The Leader for Superior Quality CS Management Center Appendix 9. Asbestos and compounds Substance CAS Number actinolite amosite anthrophyllite chrysotile crocidolite tremolite 77536-66-4 12172-73-5 77536-67-5 12001-29-5 12001-28-4 77536-68-6 Appendix 10. Formaldehyde and compounds Substance CAS Number Formaldehyde; formalin; formic aldehyde; formol 50-00-0 Appendix 11. Short-chain chlorinated paraffins (Alkane10~13 carbon chain) Substance CAS Number Short-chain Chlorintaed paraffins C10-13 Cl≥50wt % 85535-84-8 Appendix 12. Azo colorants Substance CAS Number 4-aminoazobenzene 60-09-3 o-anisidine 90-04-0 2-naphthylamine 91-59-8 3,3-dichlorobenzidine 91-94-1 4-aminodiphenyl 92-67-1 Benzidine 92-87-5 ortho-toluidine 95-53-4 4-chloro-o-toluidine 95-69-2 2,4-toluenediamine 95-80-7 ortho-Aminoazotoluene 97-56-3 5-nitro-o-toluidine 99-55-8 4,4-methylene-bis-(2-chloroaniline) 101-14-4 4,4-diaminodiphenylmethane 101-77-9 4,4-oxydianiline 101-80-4 p-chloroaniline 106-47-8 3,3-dimethoxybenzidine 119-90-4 3,3-dimethlbenzidine 119-93-7 p-cresidine 120-71-8 2,4,5-trimethylaniline 137-17-7 4,4-thiodianiline 139-65-1 2,4-diaminoanisole 615-05-4 3,3-dmethyl-4,4-diaminodiphenylmethane 838-88-0 The Leader for Superior Quality CS Management Center Appendix 13. Nickel and compounds Substance CAS Number Nickel 7440-02-0 Nickel(Ⅱ)oxide 1313-99-1 Nickel Sulfate 7786-81-4 Nickel chloride 7718--9 Other nickel compounds - Appendix 14. Organic tin compounds Substance CAS Number Tributyl tin (TBT) Triphenyl tin (TPT) Tributyl tin oxide (TBTO) Tributyl tin bromide Triphenyl tin bromide Triphenyl tin chloride Triphenyl tin hydroxide Triphenyl tin N, N' -dimethyldithiocarbamate Triphenyl tin fluoride(fentin fluoride) Triphenyl tin acetate(fentin acetate) Tributyl tin methacrylate Tributyl tin fumarate Tributyl tin fluoride Tributyl 2,3-dibromosuccinate Tributyl tin acetate Tributyl tin laurate Tributyl tin phthalate Tributyl tin sulfamate Trivutyl tin maleate Tributyl tin chloride Tributyl tin naphthenate Tributyl tin rosin salts Methyl Methacrylate and tributyl tin methacrylate 56573-85-4 668-34-8 56-35-9 1461-23-0 56-35-9 639-58-7 76-87-9 1803-12-9 379-52-2 900-95-8 18380-71-7 -35-9 1983-10-4 31732-71-5 56-36-0 3090-36-6 4782-29-0 6517-25-5 14275-57-1 1461-22-9 809-17-2 26239--5 - The Leader for Superior Quality CS Management Center
